Your logic has a few issues.
1 - Subway - the amount of open door space relative to the entire shell is small. So its not a good comparison. The gondolas open nearly a full side of the cabin
2 - The speed at which the space can be cooled again is dependent on the volume of air, how much it needs to be cooled, airflow rate, and the cooling capacity of your system. To sum up.. to cool a space fast, you use high airflow, and high cooling capacity. Both of which are energy hogs.. and neither of which are suitable for a low draw system like a recharged battery system. The subway is directly connected to a 600+V system that can supply thousands of watts of power. An AC cycle and air circulators are easily powered by such systems.
The gondolas risk loosing far more of their volume of cooled air than a subway car does simply due to the lack of containment. The only positive offset there is the volume of air to cool in the gondola is far less than a subway car. Less space to cool.. less time needed. But gondolas would still be hindered by lack of cooling capacity and airflow abilities due to their small power reserves.
A better comparison would be to something like your car. But even that has a smaller volume than a gondola, and a much higher capacity cooling system. And you can see how long it takes an AC system to bring a car down to a comfortable temperature at 'max ac'. Sit with your door open for nearly 2 mins.. and see how cool your car is.. and how long it takes to recover. It's not 'seconds'