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EPCOT at night is gorgeous, the lighting on the buildings in World Showcase are stunning. Particularly scenic is Morocco, Germany, Japan, and China.
SSE also looks wonderful at night.
The grounds of the Polynesian Resort are beautiful at night...with the tiki torches lit.
The Chinese Theatre at DHS is stunning at night, the lighting is very impressive on the building and the added neon signs are a plus.
DAK is also a very attractive location at night, but most Guests do not get to see it. The lighting on the various structures, trees, and overall nightime ambiance is breathtaking at times. The Tree Of Life looks awesome at night, as does Asia and Africa. It is a shame most Guests miss the nighttime lighting.
Tomorrowland is great at night. The place really comes to a whole new level visually at night when the lights come on. It gives it a otherworldly feeling that impresses you with images of a futuristic space port on some distant planet..or distant future.